Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

基于高斯两步移动搜寻法的村镇避难场所可达性研究

避难场所可达性是指避难场所与受灾居民之间的通达性,即灾害发生时,避难人员通过避难疏散通道到达避难场所的难易程度,是评价避难场所布局合理性的重要指标。本研究结合高斯两步移动搜寻法和网络分析法,从供需双向出发对村镇地区避难场所进行可达性分析。2种方法的结合,既充分考虑了需求点与设施点的相互作用,又充分考虑了设施点的吸引力随距离的衰减关系,并基于实际道路,以步行疏散时间作为搜索半径,降低了传统研究中因忽略供需间相互作用及实际距离而引起的可达性结果的误差。最后,以神农架松柏镇区为例,验证该方法的实际应用价值。结果表明,该方法能够有效测定村镇地区避难场所的空间可达性,同时,基于GIS软件可以直观地揭示研究区域内避难场所可达性空间分布差异。该方法可为制定科学的村镇防灾减灾规划提供方法支持。     

中国省域尺度17部门资本存量的时空特征分析

随着灾害强度、频率以及承灾体暴露的增加,自然灾害造成的损失日益严重。资本存量作为承灾体的经济暴露指标之一,是灾害损失评估的前提和基础。针对目前中国缺乏省域尺度长时间序列的经济部门分类的资本存量数据基础,论文通过永续盘存法,建立了2003—2015年中国大陆31省17部门的资本存量数据库,并分析其时空特征。结果显示：① 全国总资本存量与灾害直接损失的年际变化均呈增加趋势。省域尺度上,通过相关性分析显示,在99%置信度水平上,两者呈显著正相关(r=0.3)。② 时间上,各省17部门资本存量基本也呈增加趋势,但增速不同。在各部门增速最快的省份中,黑龙江省的居民服务、修理和其他服务业增速最快,增长约454.3倍;其次是青海省的租赁和商务服务业(398.3倍)、江苏省的金融业(295.1倍)、安徽省的科学研究和技术服务业(125.1倍)等。③ 空间上,2015年各省17部门资本存量最多的前4个部门分别是房地产业,工业,交通运输、仓储和邮政业,水利、环境和公共设施管理业,占比均在60%以上;且这4个部门资本存量暴露最多的省份是江苏省和广东省。该结果有助于从时空角度了解各省各部门资本存量暴露情况,为各省灾害风险管理者的防灾减灾工作提供重要的参考价值。     

滨海城市竖向避难场所选址可靠性评价与若干问题探讨

关注滨海城市竖向避难场所的选址可靠性问题，首先深化确立“竖向避难场所”概念；然后构建竖向避难场所选址可靠性评价模型，综合自然地理要素和建成环境要素，从与灾害直接作用相关的选址暴露性、与应急交通相关的选址敏感性、与应急服务相关的选址适应性3个维度展开，搭建3级评价指标体系；再以天津滨海新区为例、聚焦滨海城市潮洪灾害和人口安全矛盾的集核——临港城区展开实证研究，借助ArcGIS分类与可视化发现：高低可靠性选址之间具有明显的空间分异，可以分解为灾害暴露性的“近岸高?远岸低”分异、交通敏感性的“外围高?中心低”分异、服务适应性的“中心与沿河高?外围低”兼“近港高?远港低”分异。同时发现：商业设施用地选址价值较高，在高可靠性选址中占比第一；中小学和社会福利设施用地选址价值最高，在高可靠性选址中占比第二；文化科研和娱乐康体设施用地在高可靠性选址中占比最小。针对临港城区实证研究结果，提出滨海城市竖向避难场所选址及可靠性提升对策。     

西南矿区山体崩塌成因机制分析及防治对策

西南地区的矿区具有相似的地理、地质环境,通过四川芙蓉煤矿白岩崩塌的典型实例,对西南矿区山体崩塌的成灾环境进行调查研究,揭示了西南矿区山体崩塌的成因机制,并简要提出了对该煤矿开发与综合治理建议,指出了加强防治工作的紧迫性,强调开展系统工程防灾的重要性,并为该煤矿解决正常采掘接替及工作面的布置问题作出了科学的指导.     

西宁盆地泥石流类型及其防治意见

概略地叙述了西宁地区的泥石流形成条件和形成机理,并将西宁地区泥石流划分为稀性泥石流类及泥石质泥石流种类。在此基础上提出防治泥石流灾害的意见。     

The Roche Limit

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.     

板翅式换热器综合性能优化的设计方法

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。     

DISASTER ANALYSIS AND COUNTERMEASURES OF LAND SUBSIDENCE CAUSED BY COAL CUTTING IN CHINA

In recent years, many coal-producing countries have paid great attention to the land subsidence causedby coal cutting. In China, because of the dense population in coalfield areas, the land subsidence hazard is more seri-ous. After a brief analysis on the mechanism of land subsidence, this paper gives a comprehensive and systematical ac-count on all kinds of hazards caused by the land subsidence in China. The study shows that land subsidence has endan-gered land, buildings, traffic and communication lines, dykes and dams. It also causes damage to ecological and socialenvironment. In order to lessen the hazard of land subsidence, preventive measures should be taken to reduce the col-lapse amount, such as extraction with stowing, banded mining system, succession and coordination mining system, orhigh-pressure mudflow between rock strata. Measures of reinforcing or moving certain buildings should also be taken toreduce the destructive degree. In order to harness the subsidence land and bring them under control for fanning, mea-sures should be taken such as filling with spoil or fine breeze, excavating the deeper and covering the shallower land.     

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。